Sacrament of Reconciliation
"Those who approach the sacrament of Penance obtain pardon from God's mercy for the offense committed against him, and are, at the same time, reconciled with the Church which they have wounded by their sins and which by charity, by example, and by prayer labors for their conversion." (Catechism of the Catholic Church, paragraph 1422)
Reconciliation at Saint Alphonsus Liguori:
Confession (also known as penance and reconciliation) forgives any sins committed after baptism. If you are not repentant, then you are not forgiven. Only a Bishop or a priest can absolve sins in Confession. An actual mortal sin occurs when one does something that is seriously immoral, with full deliberation and knowledge. To be forgiven, admit your sin in Confession, with true sorrow (regret for sin) and repentance (a turning away from sin, toward the love of God and neighbor). Confession restores the state of salvific grace lost by actual mortal sin.
Sacrament of Anointing (Anointing of the Sick)
"Is anyone among you sick? Let him bring in the presbyters of the Church and let them pray over him, anointing him with oil in the name of the Lord. And the prayer of faith will save the sick man and the Lord will raise him up and if he be in sins, they shall be forgiven him" (James 5:14-15).
Anointing at Saint Alphonsus Liguori:
Anointing of the sick grants spiritual aid, strength and restores one with spiritual health which may include a remission of sins. Oil blessed by a bishop is place by a priest on the forehead and hands (or other suitible part if necessary).